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'Cellulose nitrate was used to make dice from the late 1860s until the mid twentieth century, and remains stable for decades. Nitric acid is released in a process called outgassing. The dice cleave, crumble, and then implode.' Deception, Fate & Rotten Luck by Ricky Jay and Rosamond Purcell
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What’s happening with the apparently fuzzy looking die in the second image?
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Crystallization of the materials, possibly a reaction of the paint used in the pips to the offgassing.