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TIL I learned about Colobopis explodens (yes, that’s really their name) ants If attacked, they bite the predator, angle their bottoms towards it, and explode. The exploding ant dies, but releases a toxic, spicy-scented yellow substance which also kills the predator, protecting the colony
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Even more interestingly, having poked around a bit in the literature, it looks like two major components of the yellow goo are: E-2-ethyl-2-hexen-1-ol 4-hydroxymellein And neither of these have been found in insects before (Melleins are toxic compounds typically produced by moulds)
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Oooooh, so do they harvest mold for the chemicals, or is the mold growing inside the ants? This is so cool!
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I'm not sure, but if I had to guess, I'd say they eat it and excrete it – that's often how it works